a number of redox-active coordination polymers (cps) or metal-organic frameworks (mofs) have been successfully synthesized using transition metals and bridging ligands. this article aims to deal with gathering the aforementioned disperse issues regarding the electroactive cps. it also goes towards illustrating the effects of various factors on the electrochemical behavior of cps including natur...

A number of redox-active coordination polymers (CPs) or metal- organic frameworks (MOFs) have been successfully synthesized using transition metals and bridging ligands. This article aims to deal with gathering the aforementioned disperse issues regarding the electroactive CPs. It also goes towards illustrating the effects of various factors on the electrochemical behavior of CPs including...

New coordination polymer of [HgLCl2]n (1) with HgCl2 and Schiff base bidentate ligand (4-methoxyphenyl) pyridine-2yl methyleneamine (L) was prepared and structurally characterized. In the 1D network structure of 1, the mecury (II) ion adopts an HgN2Cl3 distorted square pyramid geometry. In this complex, one of the chlorine acts as bridging ligand connecting two adjacent mercury(II) ions while, ...

The title dinuclear titanocene, [Ti(2)(C(8)H(9)O)(C(18)H(25)Si)(2)Cl(3)O], contains one Ti atom tetra-hedrally coordinated by two Cl atoms, a bridging O atom and the substituted cyclo-penta-dienyl ligand, and another Ti atom tetra-hedrally coordinated by a Cl atom, a bridging O atom, the 2,6-dimethyl-phenolate ligand and the substituted cyclo-penta-dienyl ligand. The bridging O atom lies on a t...

Highly efficient photoswitching tetranuclear rhenium(I) tricarbonyl diimine complexes with a stilbene-like bridging ligand are reported. The ability to directly populate excited states localized on the bridging ligand is the key for the observed efficient photoisomerization.

Abstract Hydrothermal synthesis, crystal structure and properties of a new heterometallic coordination polymer [(VO(terpy)) 4 (MoO ) 2 (Mo 8 O 26 )]·2H ( 1 (terpy = 2,2′;6′,2″-terpyridine) are reported. Compound contains two crystallographically unique vanadium(IV) atoms, bonded to terminal oxido ligand further coordinated terpy ligand. The three N atoms occupy the meridional sites distorted {V...

For the first time, a NiN2S2 metallothiolate ligand is used as a bidentate bridging ligand for a multiply bonded dimetal unit.